The arXiv preprint (abs/2605.28847, v1, May 2026) by Kenzo Ishikawa presents the first absolute calculation of Rayleigh scattering transition probabilities that includes a novel long-range quantum correlation term. This term, absent from classical treatments, produces intercorrelations across macroscopic distances in atmospheric molecules and nanoparticles, potentially explaining both the observed blue-sky intensity and anomalous laser-scattering spectra. The work is entirely theoretical, deriving probabilities from quantum mechanics without new experimental data or sample sizes; its predictions for Earth’s albedo match satellite observations but remain untested in controlled settings. As a preprint it has not undergone peer review. Classic Rayleigh (1871) and Mie theories captured intensity scaling yet left the diffusion mechanism and certain laser anomalies unresolved; this calculation supplies a missing collective coherence channel that scales from single-molecule dipoles to atmospheric volumes. Related experimental work on superradiance in dilute gases (e.g., Gross & Haroche, 1982) and recent nanoparticle coherence studies (e.g., Phys. Rev. Lett. 2023 on collective scattering) suggest the same correlation physics could appear in engineered systems. If verified, the result reframes coherence as capable of bridging microscopic quantum rules to visibly macroscopic optical phenomena, an implication mainstream coverage of atmospheric optics has overlooked.