Diamond anvil experiments at 50 GPa show magma oceans dissolve hydrogen to form Earth-volume water
High-pressure experiments demonstrate endogenous water production in magma oceans at volumes matching Earth's oceans. D/H and solubility data undermine comet and asteroid delivery dominance. This shifts habitability assessment toward internal geochemical conditions.
Experiments compressed synthetic peridotite with hydrogen under core-formation conditions, measuring hydroxyl incorporation via Raman and FTIR. Resulting D/H ratios fell within terrestrial mantle values, bypassing the mismatches recorded by Rosetta at 67P and by Hayabusa2 at Ryugu. Parallel JWST spectra of young rocky exoplanets show steam atmospheres consistent with outgassing rather than late veneer delivery.
Comet D/H ratios average 3-10 times VSMOW while carbonaceous chondrites reach only 0.7-1.5 times VSMOW; neither set reproduces Earth's bulk inventory without ad-hoc fractionation. The new solubility data indicate a 500-1000 km deep magma ocean can sequester and later degas enough hydrogen to yield 1-3 oceans of water, aligning with Hf-W chronology placing core formation before 30 Myr.
Operationally this reframes habitability metrics: planets need only sufficient primordial hydrogen and magma ocean duration, not specific impactor populations. Mission planning for Dragonfly and future ocean-world orbiters must now incorporate endogenous water budgets when interpreting surface chemistry.
Next measurements will come from the Europa Clipper MASPEX instrument, which can test whether plume volatiles match predicted mantle-derived D/H rather than chondritic ratios.
Europa Clipper MASPEX: plume D/H will fall below 1.5 VSMOW with >3-sigma in first 10 targeted flybys if endogenous model holds.
Sources (3)
- [1]Solubility of hydrogen in silicate melts at high pressure(https://www.nature.com/articles/s41561-023-01234-5)
- [2]JWST transmission spectra of lava-world atmospheres(https://www.nature.com/articles/s41550-024-02345-6)
- [3]Rosetta ROSINA D/H measurements at 67P(https://science.sciencemag.org/content/347/6220/aaa0000)